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CPID

Health effects of consumer products

Monsanto Far-Go Herbicide (agricultural)

• Chemical Composition/Ingredients

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

  Advanced
  Primary Chemical Name is the standard name assigned to a chemical substance. Chemical	Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.  CAS No./ID	Percent of chemical in preparation. % Conc.		Chemical of Concern (CoC) Chemical of Concern(CoC)
  Triallate	002303-17-5	46.3		Yes  MN-01-Minnesota Toxic Free Kids, CHC  CoC List
  Emulsifier(s) (unspecified)	999999-58-8	<5		No
  Solvent naphtha, petroleum, light aromatic	064742-95-6	<40-46		Yes  NY-02: EU-CMR Category 1A/1B Annex VI Chemical CA-02: EU-CMR Category 1A/1B Annex VI Chemical  CoC List
  Extracts, petroleum, heavy naphtha solvent	064741-98-6	<40-46		No
  1,2,4-Trimethylbenzene	000095-63-6	<18		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-15: California State Water Resources Board, Drinking Water NL CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-16-California State Water Resources Board, Drinking Water NL  CoC List
  Trimethylbenzenes (mixed isomers)	025551-13-7	<18		No
  Xylene (mixed isomers)	001330-20-7	<8		Yes  NY-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical NY-09: ATSDR Neurotoxicants NY-16: California Title 22 Chemical Exceeding MCLs NY-17: California Toxic Air Contaminant Chemicals (TACs) CA-04: EPA-IRIS, Neurotoxicity Reference Dose Chemical CA-10: ATSDR Neurotoxicants CA-17-California Title 22 Chemicals Exceeding MCLs CA-18-California Toxic Air Contaminant Chemicals (TACs) MN-01-Minnesota Toxic Free Kids, CHC CA-20-California OEHHA Non-Cancer End Points Listed Chemicals NY-19: California OEHHA Non-Cancer End Points Listed Chemical  CoC List
  Cumene	000098-82-8	<3		Yes  NY-01: California Prop. 65 Chemical NY-08: IARC Group 1, 2A & 2B Carcinogens NY-14: NTP 15th. Report on Carcinogens NY-15: California State Water Resources Board, Drinking Water NL NY-17: California Toxic Air Contaminant Chemicals (TACs) NY-20:CA Environmental Biocontaminant Monitoring Program Priority Chemical NY-23: AOEC Asthmagens CA-01-California Prop. 65 Chemicals CA-09-IARC Group 1, 2A & 2B Carcinogen CA-15-NTP 15th. Report on Carcinogens CA-16-California State Water Resources Board, Drinking Water NL CA-18-California Toxic Air Contaminant Chemicals (TACs) CA-21-California Environmental Biocontaminant Monitoring Program Priority Chemicals MN-01-Minnesota Toxic Free Kids, CHC  CoC List
   
  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID headings to sort values.
  

  Primary Chemical Name is the standard name assigned to a chemical substance.

  Chemical

  Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture.  CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
  
  We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers. 

  CAS No./ID

  Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
  EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
  ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
  NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-x

  EC No.

  Percent of chemical in preparation.

  % Conc.

  The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
  The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.

   UN Global Harmonization Classification

  Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:

  • Physical Hazard Codes (H200 series)
  • Health Hazard Codes (H300 series)
  • Environmental Hazard Codes (H400 series)
  • Supplementary Hazard Codes (EUH series)

  Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Hazard Statement Code

  Precautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
  Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.

  Precautionary Code

  Pictogram

  SVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
  1.  Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
  2.  Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
  3.  Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).

  SVHC?

  Triallate	002303-17-5	218-962-7	46.3	H302 H373 ** H317 H410 ------- No
  Emulsifier(s) (unspecified)	999999-58-8	--	<5	-------- ------- ---- No
  Solvent naphtha, petroleum, light aromatic	064742-95-6	265-199-0	<40-46	H304, H340, H350 ------- No
  Extracts, petroleum, heavy naphtha solvent	064741-98-6	265-099-7	<40-46	H410, H372, H361, H350, H340, H336, H335, H332, H302, H319, H315, H304 P391, P273, P331, P301+P310, P305+P351+P338, P302+P352, P280, P202 No
  1,2,4-Trimethylbenzene	000095-63-6	202-436-9	<18	H226, H332, H319, H335, H315, H411 P210, P243, P280, P261, P302+P352, P305+P351+P338, P273, P391 No
  Trimethylbenzenes (mixed isomers)	025551-13-7	--	<18	-------- ------- ---- No
  Xylene (mixed isomers)	001330-20-7	215-535-7	<8	H226, H312, H332, H315 P210, P243, P260, P280, P303+P361+P353, P332+P313 No
  Cumene	000098-82-8	202-704-5	<3	H412, H226, H304, H335 P273, P210, P281, P301+310, P304+P340, P303+P361+P353, P403+P235, P501 No

   

  Click on each chemical for information on chemical structure, properties and health effects.
  Click on Chemical, CAS No./ID or EC No. headings to sort values.
  

   

  Sources for Chemical Classifications

  • European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
  • European Chemicals Agency, http://echa.europa.eu/
       ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
• • Health Effects Information

    • Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Material Safety Data Sheet (MSDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.

    • Date that Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was issued by manufacturer of product. MSDS DATE :

      April 01, 1999

    • 	Health	Flammability	Reactivity
      HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product. HMIS RATING	N	N	N

    • Warnings

      Warning: Hazards to Humans and Domestic Animals Keep out of reach of children. CAUTION! CAUSES EYE IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. HARMFUL IF SWALLOWED OR INHALED. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. Avoid contact with eyes, skin or clothing. Avoid breathing vapors or spray mist.

    • Acute health effects

      From MSDS LIKELY ROUTES OF EXPOSURE: skin contact and inhalation EYE CONTACT: May cause pain, redness and tearing based on toxicity studies. Direct contact or excessive exposure to the hydrocarbon solvent vapors may result in eye irritation. SKIN CONTACT: No more than slightly toxic based on toxicity studies. Prolonged or repeated contact with the hydrocarbon solvents in this product may cause pain, redness and dry skin. INGESTION: No more than slightly toxic based on toxicity studies. No significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed. Coughing, choking and shortness of breath may occur if material is accidentally drawn into the lungs during swallowing or vomiting. This product contains hydrocarbon solvents and an emulsifier which if swallowed, may result in stomach upset with nausea and vomiting, and central nervous system (CNS) depression including headache, dizziness, fatigue, and with more severe exposures, incoordination, and unconsciousness. INHALATION: No more than slightly toxic if inhaled based on toxicity studies. Inhalation of the hydrocarbon solvent vapors may be irritating to the respiratory tract. Prolonged or excessive inhalation of the hydrocarbon solvent vapors in the product may result in CNS depression.

    • Chronic health effects

      From MSDS EYE CONTACT: Direct contact or excessive exposure to the hydrocarbon solvent vapors may result in eye irritation. SKIN CONTACT: Prolonged or repeated contact with the hydrocarbon solvents in this product may cause pain, redness and dry skin. INHALATION: Prolonged or excessive inhalation of the hydrocarbon solvent vapors in the product may result in CNS depression.

    • Carcinogenicity

      From MSDS None given

    • Handling information

      From MSDS Avoid contact with eyes, skin or clothing. Avoid breathing vapors or spray mist. User should wash hands before eating, drinking, chewing gum, using tobacco, or using the toilet. Do not use, pour, spill or store near heat or flame. Use only with adequate ventilation. Do not apply directly to water, or to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment washwaters.

    • Disposal information

      From MSDS DISPOSAL CONSIDERATIONS This material when discarded is a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA), 40 CFR 261.21, due to its characteristic of ignitability, EPA hazardous waste number D001. In addition, this material when discarded is also a hazardous waste as defined by the Resource Conservation and Recovery Act (RCRA), 40 CFR 261.33, "as a discarded commercial chemical, off-specification species, container residue, or spill residue thereof", EPA hazardous waste number U389. Best Demonstrated Available Treatment (BDAT) as defined by RCRA is disposal by incineration. Dispose of in accordance with local, state and federal regulations. Wastes of this pesticide may cause eye and respiratory tract irritation and may be dangerous. Improper disposal of excess pesticide, spray mixtures, or rinsate is a violation of Federal law. If these wastes cannot be disposed of by use according to label instruction, contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste representative at the nearest EPA Regional Office for guidance. Emptied container retains vapor and product residue. Observe all labeled safeguards until container is cleaned, reconditioned or destroyed. DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER. Do not reuse containers, except in accordance with Monsanto repackaging agreement. Return empty containers per the Monsanto container return program. If not returned, triple rinse emptied bulk containers then offer for recycling or reconditioning or dispose of in a manner approved by state and local authorities. Dispose of containers as follows: Plastic Jugs - Triple rinse container. Then offer for recycling or reconditioning, or puncture and dispose of in a sanitary landfill, or by other procedures approved by state and local authorities. Metal Drums/Cans - Triple rinse container. Then offer for recycling or reconditioning or puncture and dispose of in a sanitary landfill or by other procedures approved by state and local authorities. Product which has been contaminated or is not wanted and will be discarded is classified as hazardous under the Federal Resource Conservation and Recovery Act (RCRA) and related state laws. Specific State and Federal requirements for handling and disposal will apply. State regulations may vary and State authorities should be consulted. Soil, water and other debris contaminated with this product may have to be treated as hazardous under RCRA. State or Federal authorities should be contacted for appropriate handling and disposal methods. Consult your attorney or appropriate regulatory officials for further information on such disposal.

    • First Aid

      From MSDS : IF IN EYES: Immediately flush with plenty of water for at least 15 minutes. Get medical attention. IF INHALED: Remove individual to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. Get medical attention. IF SWALLOWED: Do NOT induce vomiting. Give large quantities of water. Get medical attention. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. NOTE: For additional human emergency first aid or treatment guidance, call collect, anytime, day or night (314) 694-4000.